A Chemical turnstile

A chemical turnstile is a device for transporting small, well-characterised doses of atoms from one location to another. A working turnstile has yet to be built, despite the numerous technological applications available for such a device. The key difficulty in manufacturing a chemical turnstile is finding a medium which will trap and transport atoms. Here we propose that ferroelastic twin walls are suitable for this role. Previous work shows that twin walls can act as two-dimensional trapping planes within which atomic transport is fast. We report simulations showing that a stress-induced reorientation of a twin wall can occur. This behaviour is ideal for chemical turnstile applications.Comment: 2 pages, 3 figure

Heat transport by phonons and the generation of heat by fast phonon processes in ferroelastic materials

Thermal conductivity of ferroelastic device materials can be reversibly controlled by strain. The nucleation and growth of twin boundaries reduces thermal conductivity if the heat flow is perpendicular to the twin wall. The twin walls act as phonon barriers whereby the thermal conductivity decreases linearly with the number of such phonon barriers. Ferroelastic materials also show elasto-caloric properties with a high frequency dynamics. The upper frequency limit is determined by heat generation on a time scale, which is some 5 orders of magnitude below the typical bulk phonon times. Some of these nano-structural processes are irreversible under stress release (but remain reversible under temperature cycling), in particular the annihilation of needle domains that are a key indicator for ferroelastic behaviour in multiferroic materials

Avalanche criticality in the martensitic transition of Cu67.64Zn16.71Al15.65 shape-memory alloy: a calorimetric and acoustic emission study

The first-order diffusionless structural transition in Cu67.64Zn16.71Al15.65 is characterized by jerky propagation of phase fronts related to the appearance of avalanches. In this paper, we describe a full analysis of this avalanche behavior using calorimetric heat-flux measurements and acoustic emission measurements. Two different propagation modes, namely, smooth front propagation and jerky avalanches, were observed in extremely slow measurements with heating and cooling rates as low as a few 10−3 K/h. Avalanches show criticality where each avalanche leads to a spike in the heat flux. Their statistical analysis leads to a power law [P(E)∼E−ε, where P(E)dE is the probability to observe an avalanche with energy E in an interval between E and E+dE] with an energy exponent of ε=2.15±0.15 in excellent agreement with the results of acoustic emission measurements. Avalanches appear to be more common for heating rates faster than 5×10−3 K/h whereas smooth front propagation occurs in all calorimetric measurements and (almost) exclusively for slower heating rates. Repeated cooling runs were taken after a waiting time of 1 month (and an intermediate heating run). Correlations between the avalanche sequences of the two cooling runs were found for the strongest avalanche peaks but not for the full sequence of avalanches. The memory effect is hence limited to strong avalanches

Anisotropy and universality: Critical Binder cumulant of the two-dimensional Ising model

We reanalyze transfer matrix and Monte Carlo results for the critical Binder cumulant U* of an anisotropic two-dimensional Ising model on a square lattice in a square geometry with periodic boundary conditions. Spins are coupled between nearest neighboring sites and between next-nearest neighboring sites along one of the lattice diagonals. We find that U* depends only on the asymptotic critical long-distance features of the anisotropy, irrespective of its realization through ferromagnetic or antiferromagnetic next-nearest neighbor couplings. We modify an earlier renormalization-group calculation to obtain a quantitative description of the anisotropy dependence of U*. Our results support our recent claim towards the validity of universality for critical phenomena in the presence of a weak anisotropy.Comment: 4 pages, 2 figures; one reference and some clarifications adde

OH species, U ions, and CO/CO2 in thermally annealed metamict zircon (ZrSiO4)

Metamict zircon crystals have been thermally annealed between 500 and 1800 K and analyzed\ud using infrared and optical spectroscopy in the spectral region of 1400–7000 cm–1. Recrystallization\ud and dehydroxylation via complex proton/OH diffusion, redistribution, and incorporations of additional\ud hydrogen-related species within the crystal structure of zircon occur at temperatures above 700 K\ud in partially metamict zircon and above 1200 K in heavily amorphized material. Thermally induced\ud changes in O-H stretching spectra are different between E || c and E ⊥ c in weakly metamict zircon. The\ud O-H stretching band near 3342 cm–1 (with E ⊥ c) in an untreated sample shifts to 3277 cm–1 at 1200 K,\ud where the frequency of O-H stretching bands with E || c increases. Conversions of hydrogen-related\ud species were observed and extra OH bands were found at temperatures between 1200 and 1600 K. A\ud dramatic change of OH spectra was recorded between 1600 and 1800 K in partially metamict crystals,\ud resulting in additional absorption features (near 3098 and 2998 cm–1 along E ⊥ c). U4+ and U5+ related\ud spectra are also affected by high-temperature annealing. For highly metamict zircon, the U4+ band\ud near 4830 cm–1 shows an increase in intensity above 1200 K. Additional IR bands at 2146 and 2344\ud cm–1 appear in the spectra of metamict zircon annealed at high temperatures. Their frequencies are\ud consistent with stretching vibrations of CO and CO2

Strain-induced interface reconstruction in epitaxial heterostructures

We investigate in the framework of Landau theory the distortion of the strain fields at the interface of two dissimilar ferroelastic oxides that undergo a structural cubic-to-tetragonal phase transition. Simple analytical solutions are derived for the dilatational and the order parameter strains that are globally valid over the whole of the heterostructure. The solutions reveal that the dilatational strain exhibits compression close to the interface which may in turn affect the electronic properties in that region.Comment: 7 pages, 5 figures, to be published in Physical Review

Domain glass

Microstructural patterns of twin boundaries and tweed in ferroelastic materials display typical aspects of glasses. The patterns are complex, their dynamics follows Vogel–Fulcher statistics and their field cooling–non-field cooling hysteresis is similar to those described in this issue as ‘strain glasses’. The difference is that domain glasses do not need extrinsic defects to form. In the paraelastic phase, an intrinsic tweed pattern dominates the high temperature precursor regime. Experimentally, massive elastic precursor softening is related to polar standing waves, which are attributed to the glassy relaxation of the tweed pattern. In the ferroelastic phase we find a complex twin pattern when the sample is strained with a constant strain rate. The dynamics of the pattern formation is a-thermal at low temperatures and follows Vogel–Fulcher statistics at moderately high temperatures. It is argued that domain boundary patterns can hence evolve glass-like states while the underlying matrix remains fully crystalline without any defect induced disorder

Correlations between Elastic, Calorimetric, and Polar Properties of Ferroelectric PbSc0.5Ta0.5O3 (PST)

Calorimetric, elastic, and polar properties of ferrolectric lead scandium tantalate PbSc0.5Ta0.5O3 (PST) with 65% cation order have been investigated in the vicinity of the paraelectric-ferroelectric transition at Ttrans = 295K. Comparison of temperature dependencies of the excess specific heat and elastic properties indicate that both anomalies stem from ther- mal fluctuations of order parameters in three dimensions. These fluctuations are consistent with tweed microstructure. This transition is driven by several coupled thermodynamic order parameters, as evidenced by a strongly non-linear scaling of the excess entropy with the squared ferroelectric polarization.National Natural Science Foundation of China (51850410520, 51320105014 and 51621063

Tin telluride: a weakly co-elastic metal

We report resonant ultrasound spectroscopy (RUS), dilatometry/magnetostriction, magnetotransport, magnetization, specific heat, and $^{119}$Sn M\"ossbauer spectroscopy measurements on SnTe and Sn$_{0.995}$Cr$_{0.005}$Te. Hall measurements at $T=77$ K indicate that our Bridgman-grown single crystals have a $p$-type carrier concentration of $3.4 \times 10^{19}$ cm$^{-3}$ and that our Cr-doped crystals have an $n$-type concentration of $5.8 \times 10^{22}$ cm$^{-3}$. Although our SnTe crystals are diamagnetic over the temperature range $2\, \text{K} \leq T \leq 1100\, \text{K}$, the Cr-doped crystals are room temperature ferromagnets with a Curie temperature of 294 K. For each sample type, three-terminal capacitive dilatometry measurements detect a subtle 0.5 micron distortion at $T_c \approx 85$ K. Whereas our RUS measurements on SnTe show elastic hardening near the structural transition, pointing to co-elastic behavior, similar measurements on Sn$_{0.995}$Cr$_{0.005}$Te show a pronounced softening, pointing to ferroelastic behavior. Effective Debye temperature, $\theta_D$, values of SnTe obtained from $^{119}$Sn M\"ossbauer studies show a hardening of phonons in the range 60--115K ($\theta_D$ = 162K) as compared with the 100--300K range ($\theta_D$ = 150K). In addition, a precursor softening extending over approximately 100 K anticipates this collapse at the critical temperature, and quantitative analysis over three decades of its reduced modulus finds $\Delta C_{44}/C_{44}=A|(T-T_0)/T_0|^{-\kappa}$ with $\kappa = 0.50 \pm 0.02$, a value indicating a three-dimensional softening of phonon branches at a temperature $T_0 \sim 75$ K, considerably below $T_c$. We suggest that the differences in these two types of elastic behaviors lie in the absence of elastic domain wall motion in the one case and their nucleation in the other